SINGLE ENANTIOMER PROPELLER-SHAPED POLYNUCLEAR COMPLEXES AS CATALYSTS-PROOF-OF-CONCEPT FOR ENANTIOINDUCTION IN A MICHAEL ADDITION REACTION

Single enantiomer propeller-shaped polynuclear complexes as catalysts-proof-of-concept for enantioinduction in a Michael addition reaction

We report a family of propeller-shaped polynuclear metal complexes whose overall chirality is dictated by a single stereogenic Beverage Centre centre within their component amino alcohol-ligand.These topologically intriguing complexes are readily prepared in enantiomerically pure form and are shown here to catalyse the conjugate addition of barbitu

read more

The rotational atherectomy with a guide extension catheter for calcified and tortuous lesions in left anterior descending artery: a case report

Abstract Background The interventional treatment of calcified lesions with severe tortuosity in the left anterior descending artery (LAD) was challenging and the report of rotational atherectomy with mother-and-child technique has Bucket Hats been scarce.Case presentation An 84-year-old woman was hospitalized for non-ST-segment acute coronary syndr

read more

Estimating private sector out-of-pocket expenditures on family planning commodities in low-and-middle-income countries

Introduction The role of the private sector in family planning (FP) is well studied; however, few efforts have been made to quantify the role of private out-of-pocket (OOP) expenditures on FP commodities across low-and-middle-income countries (LMICs).Calculating OOP expenditures is important to illuminate the magnitude of these contributions and to

read more